Hmm, I noticed I didn't directly answer the questions:

What is Vader’s Path to Victory?
It varies depending on his opponent, which is what I consider a strength of his deck. Against a character without power D, it's the attacks of the red deck with the finishing power of TD. Against personality minor opponents, it's hide behind stormtroopers until Chokes eliminate the possibilities of the opponent. I guess overall I'd say Vader's PtV is annoyance -- do what your opponent doesn't want, whether it's slowly chipping away at health by DD or hampering their efforts by eliminating the asset of a personality minor.

... Path Resources?

Throw Debris is obviously huge, but Chokes play an important role as well in Vader's versatility. YSANC plays into the "annoyance" PtV well against most opponents. Wrath is more of a sponge than Chokes because, although they do damage the major, the high damage of Choke is more effective against personality minors, while against weak generics, DSD is better than using the Wrath to kill them.

[A]re his archetypes rearrangeable into a more successful Path?

Drop 2 Wraths and add a Throw Debris doesn't change his DD to the major, and then toss in another DSD to make up for the damage that would probably be done to a minor. That's keeping at least one of every card still in there; eliminating the other Wrath in favor of something else is also a possibility if not all are to be included.

In Italy for thirty years under the Borgias they had warfare, terror, murder, bloodshed, but they produced Michelangelo, Leonardo da Vinci, and the Renaissance. In Switzerland they had brotherly love, they had five hundred years of democracy and peace. And what did that produce? The cuckoo-clock.
- Orson Welles